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Also Yan et al. discussed several instances of compound degradation due to hydrolysis and oxidation mechanisms,21 while Darvas et al. demonstrated the stability of a combinatorial library containing a labile core structure with an electro-rich pyrrole moiety could be improved by using electronwithdrawing or bulky substitution.8 Cheng et al. observed several elimination reactions, such as loss of 17 Da (water), 17 Da (ammonia), 36 Da (HCl), and 28 Da (CO).19 In contrast, very few direct oxidation products were observed (e.g., +16, +32 Da) in their study, Table 13.3, and these results correlate well with the observation that the water content in the sample has a more signi cant effect on compound stability than the atmospheric oxygen content. Figure 13.11 gives an example of the degradation products observed for the compounds in this study. Additionally many compounds showed a signi cant decrease in concentration, with no new components identi ed in the UV or MS chromatograms. 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22 Apr 2014 ... I have 508 items I need to create a UPC number for using a GTIN 12 calculation as the SKU's are 11 digits long. Any help on a an excel formula ...
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